1) Synthesis of biobased polyacetals: A review.
Renner, A.; Thorat, S. S.; Sibi, M.P. RSC Sustain. 2024, (Accepted).
2) Relay-PHOS. Ligands with fluxional chirality in asymmetric palladium-catalyzed allylic alkylation.
So, R. C.; Subramanian, H.; Kuhen, C.; Sibi, M. P. Org. Lett. 2024, 26, 7196–7201.
3) Tough Bio-based Thermosets with Dual Curing Capability via Epoxy and Allylic Functionality.
Bohdan, D.; Poulin, Y.; Thorat, S.; Sibi, M. P.; Voronov, A. Prog Org Coat 2024, 197, 108844.
4) Techno Economic Assessment and Carbon Pricing Analysis for Economic Feasibility of Epoxidized Sucrose Soyate: A Biobased Thermoset Resin.
Shokoofeh, G.; Pourhashem, G.; Sibi, M. P.; Webster, D. C. J. Clean. Prod. 2024, 469, 143148. https://doi.org/10.1016/j.jclepro.2024.143148
5) Furan-rich, Biobased Transfection Agents as Potential Candidates for Intracellular Plasmid DNA Delivery.
Hoque, A. A.; Kannaboina, P.; Abraham Y.; Mehedi, M.; Sibi, M. P.; Quadir, M. J. RSC Adv. 2024, 14, 32637-32647
(https://doi.org/10.1039/D4RA05978F).
6) Vanillin-Derived Veratrole Reactive Diluents in Stereolithography
Hevus, I.; Tiwari, S.; Thorat S.S.; Gibbon, L.R.; La Scala, J.J.; Ulven, C.A.; Sibi, M.P.; Webster, D.C. ACS Appl. Polym. Mater. 2024, 6, 7705-7715.
7) Unveiling the Beauty of Cyclopropane Formation: A Comprehensive Survey of Enantioselective Michael Initiated Ring Closure (MIRC) Reactions.
Ramkumar, M.; Biosawe, W.; Thorat, S. S.; Sibi, M.P. Org. Chem. Front. 2024, 11, 4560-4601.
8) Enantioselective enolate protonations: Evaluation of achiral templates with fluxional brønsted basic substituents in conjugate addition of malononitriles.
Reimann, S.; Adachi, S.; Subramanian, H.; Sibi, M. P. Tetrahedron, 2024, 152, 133833.
9) A Preliminary Study of Thermosets from Epoxy Resins Made Using Low-Toxicity Furan-Based Diols.
Shafranska, O.; Sutton, C.; Kalita, D.; Kannaboina, P.; Tiwari, S.; Sibi, M. P.; Webster, D. C. Macromol. Rapid Commun., 2024, 2300665.
10) Zinc/Bismuth-Mediated Allylation Reaction of Biomass Feedstocks: Synthesis of Furanic Diols.
Biswas, S.; Kannaboina, P.; Sibi, M. P. Synthesis, 2024, 56, 1807-1814.
11) Total Synthesis of Natural Products Containing the Tetralone Subunit.
Thorat, S. S.; Sibi, M. P. Arkivoc 2024, 202312053.
1) Free Radical (Co)Polymerization of Aromatic Vinyl Monomers Derived from Vanillin.
Polunin, Y.; Domnich, B.; Tiwari, S.; Thorat, S. S.; Sibi, M. P.; Voronov, A., Eur. Polym. J., 2023, 201, 112546.
2) Furanic (Meth)acrylate Monomers as Sustainable Reactive Diluents for Stereolithography.
Hevus, I.; Kannaboina, P.; Qian, Y.; Wu, J.; Johnson, M.; Gibbon, L.; La Scala, J. J. ; Ulven, C.; Sibi, M. P.; Webster, D. C. ACS Appl. Polym. Mater. 2023, 5, 9659–9670.
https://doi.org/10.1021/acsapm.3c02207
3) Stereoselective Hydrogen Atom Transfer in Free Radical Chemistry. Subramanian, H.; Sibi, M. P. Asian J. Org. Chem. 2023, 12, e202300175.
https://doi.org/10.1002/ajoc.202300175
1) Poly (vinyl ethers) based on the biomass-derived compound, eugenol, and their one-component, ambient-cured surface coatings.
Kalita, D.; Tarnavchyk, I.; Selvakumar, S.; Chisholm, B.; Sibi, M. P.; Webster, D. C. Prog. Org. Coat., 2022, 170, 106996.
2) Enantioselective Radical Reactions Using Chiral Catalysts.
Mondal, S.; Dumur, F.; Gigmes, D.; Sibi, M. P.; Bertrand, M.; Nechab, M. Chem. Rev. 2022, 122, 5842-5976.
https://doi.org/10.1021/acs.chemrev.1c00582
3) Towards Upcycling Biomass-Derived Crosslinked Polymers with Light.
Singathi, R.; Raghunathan, R.; Krishnan, R.; Kumar R., S.; Baburaj, S.; Sibi, M.P.; Webster, D.C.; Sivaguru, J. Angew. Chemie, Int. Ed., 2022, 61, e202203353.
https://doi.org/10.1002/anie.202203353
1) Bio-Based Furanic Di(meth)acrylates as Reactive Diluents for UV Curable Coatings: Synthesis and Coating Evaluation.
Wu, J.; Qian, Y.; Sutton, C. A.; La Scala, J. J.; Webster, D. C. ; Sibi, M. P. ACS Sustainable Chem. Eng. 2021, 9, 15537-15544.
https://doi.org/10.1021/acssuschemeng.1c05588
2) Propargyl Radicals in Organic Synthesis.
Muresan, M. ; Subramanian, H. ; Sibi, M. P. ; Green, J. R. Eur. J. Org. Chem. 2021, 22, 3359-3375.
https://doi.org/10.1002/ejoc.202100367
3) The Size-Accelerated Kinetic Resolution of Secondary Alcohols.
Poelloth, B.; Sibi, M. P. ; Zipse, H. Angew. Chemie, Int. Ed. 2021, 60, 774-778.
https://doi.org/10.1002/anie.202011687
1) Novel Biobased Furanic Diols as Potential Alternatives to BPA: Synthesis and Endocrine Activity Screening.
Sutton, C. A.; Polykarpov, A.; van den Berg, K.; Yahkind, A.; Lea, L. J. Webster, D. C.; Sibi, M. P. ACS Sustainable Chem. Eng. 2020, 8, 18824−18829.
https://dx.doi.org/10.1021/acssuschemeng.0c08207
2) A Preliminary Environmental Assessment of Epoxidized Sucrose Soyate (ESS)–Based Biocomposite.
Ghasemi, S.; Sibi, M. P.; Ulven, C. A.; Webster, D. C.; Pourhashem, G. Molecules, 2020, 25, 2797.
https://doi.org/10.3390/molecules25122797.
3) Structurally Unique PARP-1 Inhibitors for the Treatment of Prostate Cancer.
Divan, A.; Sibi, M. P.; Tulin, A. Pharmacol Res Perspect. 2020, 8, e00586.
https://doi.org.10.1002/prp2.586
1) Biobased, Non-Isocyanate, 2K Polyurethane Coatings Produced from Polycarbamate and Dialdehyde Crosslinking.
Silbert, S. D.; Serum, E. M.; La S. J. J.; Sibi, M. P.; Webster, D. C. ACS Sustainable Chem. Eng., 2019, 7, 19621-19630.
https://doi.org/10.1021/acssuschemeng.9b04713
2) Asymmetric Synthesis of 2,3-Disubstituted Cyclic Ketones by Enantioselective Conjugate Radical Additions.
Nad, Sukanya; Sibi, Mukund P. Helv. Chim. Acta, 2019, 102, e1900223.
https://doi.org/10.1002/hlca.201900223
3) Special issue on organic free radical chemistry.
Sibi, Mukund P.; Li, Chaozhong; Jiao, Ning. Science China: Chemistry, 2019, 62, 1423-1424.
4) New AB Type Monomers from Lignocellulosic Biomass.
Serum, E. M.; Sutton, C. A.; Renner, A. C.; Dawn, D.; Sibi, M. P. Pure Appl. Chem. 2019, 91, 389-396.
https://doi.org/10.1515/pac-2018-0913
1) Renewable Reactive Diluents as Practical Styrene Replacements in Bio-based Vinyl Ester Thermosets.
Yu, A. Z.; Serum. E. M.; Renner, A. C.; Sahouani, J. M.; Sibi, M. P.; Webster, D. C. ACS Sustain. Chem. Eng. 2018, 6, 12586-12592.
DOI:10.1021/acssuschemeng.8b03356
2) Catalyst-Free Lignin Valorization by Acetoacetylation. Structural Elucidation by Comparison with Model Compounds.
Krall, E. M.; Serum, E. M.; Sibi, M. P.; Webster, D. C. Green Chem., 2018, 20, 2959 – 2966.
3) Dynamic Kinetic Resolution of Biaryl Atropisomers by Chiral Dialkylamino Pyridine Catalysts.
Ma, G.; Deng, C.; Deng, J.; Sibi, M. P. Org. Biomol. Chem. 2018, 16, 3121-3126.
DOI: 10.1039/C8OB00384J Hot Article
4) Dibenzofuran-4,6-bis(oxazoline) (DBFOX). A Novel trans-Chelating Bis(oxazoline) Ligand for Asymmetric Reactions.
Itoh, K; Sibi, M. P. Org. Biomol. Chem. 2018, 16, 5561-5565.
DOI: 10.1039/C8OB01010B Cover article
5) Valorization of 2,5-Furandicarboxylic Acid. Diels-Alder Reactions with Benzyne.
Serum, E.M.; Sermadurai, S.; Zimmermann, N.; Sibi, M. P. Green Chem. 2018, 20, 1448-1454. DOI: 10.1039/C8GC00308D. Back Cover
6) Biobased Poly(vinyl ether)s Derived from Soybean Oil, Linseed Oil, and Camelina Oil: Synthesis, Characterization, and Properties of Crosslinked Networks and Surface Coatings.
Kalita, D.; Kalita, J.; Tarnavchyk, I.; Sibi, M. P.; Moser, B. R. Webster, D. C. Chisholm, B. J., Prog. Org. Coat., 2018, 125, 453-462.
doi.org/10.1016/j.porgcoat.2018.09.033
7) Overview of Enterolactone Biological Properties and Total Synthesis.
Waulters, Q. T.; Bio-Sawe, W.; Hofmann, R.; Sibi, M. P. ARKIVOC, 2018, part iv, 76-93.
doi.org/10.24820/ark.5550190.p010.451
8) Polymers from Bio-derived Resources: Synthesis of Poly(silylether)s from Furan Derivatives Catalyzed by a Salen–Mn(V) Complex.
Vijjamarri, S.; Streed, S.; Serum, E. M.; Sibi, M. P.; Du, G. ACS Sustainable Chem. Eng. 2018, 6, 2491-2497.
DOI: 10.1021/acssuschemeng.7b03932
9) Fine Chemicals From A Biomass-Derived Dicarboxylic Acid: Chiral Bisoxazolines And Their Application In Enantioselective Diels-Alder Reactions.
Sermadurai, S.; Fairweather, A.; Ugrinov, A.; Sibi, M. P. Heterocycles 2018, 97, 151-157.
10) Size Exclusion Chromatography of Lignin: The Mechanistic Aspects and Elimination of Undesired Secondary Interactions.
Andrianova, A. A.; Yeudakimenka, N. A.; Lilak, S. L.; Kozliak, E. I.; Ugrinov, A.; Sibi, M. P.; Kubatova, A. J. Chromatography A. 2018, 1534, 101-110.
https://doi.org/10.1016/j.chroma.2017.12.051
11) Photoacidity of Vanillin Derivatives.
Clay, A.; Krishnan, R.; Sibi, M. P.; Webster, D.; Jockusch, S.; Sivaguru, J. J. Photochem. Photobiol. A. Chemistry 2018, 35538-41.
https://doi.org/10.1016/j.jphotochem.2017.11.039
12) Directed ortho-Metalation of Aryl Amides, O-Carbamates, and Methoxymethoxy Systems: Directed Metalation Group Competition and Cooperation.
Miah, J. M. A.; Sibi, M. P.; Chattopadhyay, S.; Familoni, O. B.; Snieckus, V. Eur. J. Org. Chem. 2018, 447-454.
13) Directed ortho-Metalation of O-Aryl-N,N-Dialkylcarbamates: Methodology, Anionic ortho-Fries Rearrangement, and Lateral Metalation.
Miah, J. M. A.; Sibi, M. P.; Chattopadhyay, S.; Familoni, O. B.; Snieckus, V. Eur. J. Org. Chem. 2018, 440-446.
DOI: 10.1002/ejoc.201701142. Front Cover
1) Enantioselective and Diastereoselective Conjugate Radical Additions to α-Arylidene Ketones and Lactones.
Zhao, C.; Sibi, M. P. Synlett 2017, 2971-2975.
2) Origin of Streched-Exponential Photoluminescence Relaxation in Size-Separated Silicon Nanocrystals. Brown, S. L.; Krishnan, R.; Elbaradei, A.; Jayaraman, S.; Sibi, M. P.; Hobbie, E. AIP Adv. 2017, 7, 055314/1-055314/11.
https://doi.org/10.1063/1.4984608
3) Life Cycle Assessment of Photodegradable Polymeric Material Derived from Renewable Bioresources.
Isola, C.; Sieverding, H. L.; Raghunathan, R.; Sibi, M. P.; Webster, D. C.; Sivaguru, J.; Stone, J. J. J. Clean. Prod., 2017, 142, 2935-2944.
https://doi.org/10.1016/j.jclepro.2016.10.177.
4) Enantioselective and Diastereoselective Conjugate Radical Additions to α-Arylidene Ketones and Lactones.
Zhao, C.; Sibi, M. P. Synlett 2017, 28, 2971-2975.
5) Copper‐based Chiral Lewis Acids.
Karthikeyan, I.; Sibi, M. P. In Chiral Lewis Acids in Organic Synthesis 2017, 103-135.
https://doi.org/10.1002/9783527802142.ch4
6) Controlled photodegradation of biomass derived polymers.
R Singathi, J Sivaguru, M Sibi, D Webster. Abstract of Papers of the American Chemical Socity 254.
7) Completing the cycle: Photodegradation as a tool to make sustainable and recyclable polymers/oligomers derived from bioresources.
J Sivaguru, R Singathi, R Raghunathan, M Sibi, D Webster Abstract of Papers of the American Chemical Socity 254.
8) Origin of stretched-exponential photoluminescence relaxation in size-separated silicon nanocrystals.
SL Brown, R Krishnan, A Elbaradei, J Sivaguru, MP Sibi, EK Hobbie AIP Adv. 7 (5), 055314.
https://doi.org/10.1063/1.4984608.
9) Oxidatively-cured coatings from renewable-based poly (vinyl ether) s.
D Kalita, B Chisholm, M Sibi Abstract of Papers of the American Chemical Socity 253.
10) Bronsted-acids in template mediated asymmetric synthesis: Mechanistic understanding of azomethine imine cycloaddition reactions.
H Subramanian, M Sibi Abstract of Papers of the American Chemical Socity 253.
11) Working with challenging substrates in catalytic enantioselective reactions: Understanding cooperative modes of activation in template-based catalytic reactions.
H Subramanian, M Sibi Abstract of Papers of the American Chemical Socity 253.
12) Life cycle assessment of photodegradable polymeric material derived from renewable bioresources.
Isola, C.; Sieverding, H. L.; Raghunathan, R.; Sibi, M. P.; Webster, D. C.; Sivaguru, J.; Stone, J. J. J. Clean. Prod. 2017, 142, 2935-2944.
1) Synthesis of Silicon Quantum Dots using Cyclohexasilane (Si6H12).
Guruvenkat, S.; Hoey, J. M.; Anderson, K. J.; Frohlich, M. T.; Krishnan, R.; Sivaguru, J.; Sibi, M. P.; Boudjouk, P. J. Mater. Chem. C, 2016, 4, 8206-8213.
DOI: https://doi.org/10.1039/C6TC01435F
2) Synthesis and Characterization of Polyurethane Networks Derived from Soybean Oil-Based Cyclic Carbonates and Bio-Based Diamines.
Samanta, S.; Sermadurai, S.; Bahr, J.; Wicramaratne, D. S.; Sibi, M. P.; Chisholm, B. J. ACS Sustainable Chem. Eng. 2016, 4, 6551-6561.
https://doi.org/10.1021/acssuschemeng.6b01409
3) Oraganophotocatalysis: Insights into the Mechanistic Aspects of Thiourea-Mediated intermolecular [2+2]-Photocycloaddition.
Vallavogu, N.; Sermadurai, S.; Pemberton, B.; Jockusch, S.; Sibi, M. P.; Sivaguru, J. Angew. Chem. Int. Ed. 2016, 55, 5446-5451.
https://doi.org/10.1002/anie.201600596 Frontispiece article
4) Evaluating thiourea/urea catalyst for enantioselective 6p-photocyclization of acrylanilide.
Raghunathan, R.; Steffen Jockusch, S.; Sibi, M. P.; Sivaguru, J. J. Photochem. Photobiol., A* 2016, 331, 84-88.
https://doi.org/10.1016/j.jphotochem.2015.12.023
5) Synthesis and Characterization of Polyurethane Networks Derived from Soybean Oil-Based Cyclic Carbonates and Bio-Based Diamines.
Samanta, S.; Sermadurai, S.; Bahr, J.; Wicramaratne, D. S.; Sibi, M. P.; Chisholm, B. J. ACS Sustain. Chem. Eng. 2016, 4, 6551-6561.
https://doi.org/10.1021/acssuschemeng.6b01409
6) Oraganophotocatalysis: Insights into the Mechanistic Aspects of Thiourea-Mediated intermolecular [2+2]-Photocycloaddition.
Vallavogu, N.; Sermadurai, S.; Pemberton, B.; Jockusch, S.; Sibi, M. P.; Sivaguru, J. Angew. Chem. Int. 2016, 55, 5446-5451.
https://doi.org/10.1002/anie.201600596 Frontispiece article
1) An alternative to alkyds: Novel biobased polymers for coatings applications.
Kalita, H.; Kalita, D.; Sibi, M. P.; Chisholm, Bret J. European Coatings Journal 2015, 6, 26-29.
2) Novel bio-based polymers for coating applications. Chisholm.
Bret J.; Kalita, Harjoyti; Kalita, Deep; Alam, Samim; Chernykh, Andrey; Tarnavchyk, Ihor; Bahr, James; Samanta, Satyabrata; Jayasooriyama, Anurad; Fernando, Shashi; Proceedings of the International Waterborne, High-Solids, and Powder Coatings Symposium (2015), 42nd, 18-32.
3) Nonbiaryl and Heterobiaryl Atropisomers: Molecular Templates with Promise for Atropselective Chemical Transformations.
Kumarasamy, E.; Raghunathan, R.; Sibi, M. P.; Sivaguru, J. Chem. Rev. 2015, 15, 11239-11300.
DOI: 10.1021/acs.chemrev.5b00136
4) Linear Polyester Synthesized from Furfural-based Monomer by Photoreaction in Sunlight.
Wang, Z.; Kastern, B.; Randazzo, K.; Ugrinov, A.; Butz, J.; Seals, D.; Sibi, M. P.; Chu, Q. R. Green Chem., 2015, 17, 4720-4724.
DOI:10.1039/C5GC01783A. Cover Article
5) Catalytic Kinetic Resolution of Biaryl Compounds.
Ma. G.; Sibi, M. P. Chem. Eur. J. 2015, 21, 11644-11657. DOI:10.1002/chem.201500869. Frontispiece article
6) Structural and Solubility Parameter Correlations of Gelation Abilities for Dihydroxylated Derivatives of Long-chained, Naturally-occurring Fatty Acids.
Zhang, M.; Selvakumar, S.; Zhang, X.; Sibi, M. P.; Weiss, R. G. Chem. Eur. J. 2015, 21, 8530-8543.
7) Novel Biobased Polymers for Coatings Applications.
Kalita, H.; Alam, S.; Kalita, D.; Chernykh, A.; Tarnavchyk, I.; Bahr, J.; Samanta, S.; Jayasooriyamu, A.; Fernando, S.; Selvakumar, S.; Wickramaratne, D. S.; Sibi, M. P.; Chisholm, B. J. J Coat Technol Res, 2015, 12, 633-646. JCTR-D-14-00282R1
8) Characterization of Brønsted Acid-Base Complexes by 19F DOSY.
Subramanian, H.; Jasperse, C. P.; Sibi, M. P. Org. Lett. 2015, 17, 1429-1432.
DOI: 10.1021/acs.orglett.5b00297
9) Lewis Acid Mediated Diastereoselective Intermolecular Radical Addition/Trapping with Pyrazolidinone Acrylimides.
Ma, G.; Fujita, T.; Sibi, M. P. Tetrahedron Lett. 2015, 56, 3571-3574.
DOI:10.1016/j.tetlet.2015.02.00
10) Programmed degradation of oligomeric/polymeric materials derived from renewable bio-resources.
Rajendran, S.; Raghunathan, R.; Krishnan, R.; Hevus, I.; Ugrinov, A.; Sibi, M. P.; Webster, D. C.; Jayaraman, S. Angew. Chem. Int. 2015, 55, 1159-1163.
1) Evaluation of Achiral Templates with Fluxional Brønsted Basic Substituents in Enantioselective Conjugate Additions.
Adachi, S.; Takeda, N.; Sibi, M. P. Org. Lett. 2014, 16, 6440–6443.
https://doi.org/10.1021/ol503275w
2) Thiyl Radicals: From Simple Addition to Asymmetric Catalysis.
Subramanian, H.; Moorthy, R.; Sibi, M. P. Angew. Chem. Int. Ed. 2014, 53, 13660-13662.
3) Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts.
Ma, G.; Sibi, M. P. Org. Chem. Front. 2014, 1, 1152-1156.
DOI: 10.1039/C4QO00210E Cover Article
4) Evaluating thiourea architecture for intramolecular [2+2]-photocycloaddition of 4-alkenylcoumarins.
Vallavoju, N.; Sermaurai, S.; Jocksuch, S.; Prabhakaran, M. T.; Sibi, M. P.; Jayaraman, S. Adv. Synth. Catal. 2014, 356, 2763-2768.
5) Fluxionally Chiral DMAP Catalysts: Kinetic Resolution of Axially Chiral Biaryl Compounds.
Ma, G.; Deng, J.; Sibi, M. P. Angew. Chem. Int. Ed. 2014, 53, 11818-11821.
https://doi.org/10.1002/anie.201406684 Cover Article
6) Enantioselective organo-photocatalysis mediated by atropisomeric thiourea derivatives.
Vallavoju, N.; Sermadurai, S.; Jocksuch, S.; Sibi, M. P.; Jayaraman, S. Angew. Chem. Int. Ed, 2014, 53, 5604-5608.
7) Thermoset Coatings from Epoxidized Sucrose Soyate and Blocked, Biobased Dicarboxylic Acids.
Kovash, C. S.; Pavlacky, E.; Selvakumar, S.; Sibi, M. P.; Webster, D. C. Chem. Suss. Chem. 2014, 7, 2289-2294.
https://doi.org/10.1002/cssc.201402091
8) Regio- And Enantioselective Nitrone Cycloaddition To Alkynones For The Synthesis Of D4-Isoxazolines.
Sibi, M. P.; Dunkle, K.; Rane, D. Heterocycles, 2014, 88, 1639-1647.
9) Bio-Based Poly(vinyl ether)s and Their Application as Alkyd-Type Surface Coatings.
Kalita, H.; Selvakumar, S.; Jayasooriyamu, A.; Fernando, S.; Samanta, S.; Bahr, J.; Alam, S.; Sibi, M.; Vold, J.; Ulven, C.; Chisholm, B. J. Green Chem., 2014, 16, 1974-1986.
1) Csp3-F Bond Formation: A Free-Radical Approach.
Sibi, M. P.; Landais, Y. Angew. Chem. Int. Ed. 2013, 52, 3570-3572.
https://doi.org/10.1002/anie.201209583
2) Polyamides Based on the Renewable Monomer, 1,13-Tridecane Diamine I: Synthesis and Characterization of Nylon 13,T.
He, J.; Samanta, S.; Selvakumar, S.; Lattimer, J.; Ulven. C.; Sibi, M. P.; Chisholm, B. Green Mater., 2013, 1, 114-124.
3) Polyamides Based on the Renewable Monomer, 1,13-Tridecane Diamine I: Synthesis and Characterization of Nylon 13,6.
Samanta, S.; He, J.; Selvakumar, S.; Lattimer, J.; Ulven. C.; Sibi, M. P.; Chisholm, B. Polymer 2013, 54, 1141-1149.
1) Recent advances in nitrile oxide cycloaddition in the synthesis of 2-oxazolines. Rane, D.; Sibi, M. P. Curr. Org. Synth. 2011, 8, 616-627.
1) Addition of Free Radicals to Carbon-Carbon Multiple Bonds. Hata, S.; Sibi, M. P. Science of Synthesis, Stereoselective Synthesis I, pp 873-922, Thieme, 2010
2) 3-Isoxazolidinone: A New Achiral Template for Enantioselective Transformations. Sibi, M. P.; Gustafson, B. A.; Coulomb, J. Bull. Kor. Chem. Soc. 2010, 31, 541-542.
DOI 10.5012/bkcs.2010.31.03.541
3) Enantioselective Diels-Alder Cycloadditions with b-Substituted Pyrazolidinone Propiolimides. Sibi, M. P.; Cruz, Jr. W.; Stanley, L. M. Synlett 2010, 889-892.
1) Recent Developments in the Construction of Quaternary Stereocenters via Cycloadditions. Rane, D.; Sibi, M. P. Chemistry Today, 2009, 27, 14-16.
2) Nitrile Ylides: Diastereoselective Cycloadditions using Chiral Oxzolidinones Without Lewis Acid. Sibi, M. P.; Soeta, T.; Jasperse, C. P. Org. Lett. 2009, 11, 5366–5369.
https://doi.org/10.1021/ol9018584
3) A Diels-Alder Cycloaddition Strategy for the Kinetic Resolution of Chiral Pyrazolidinones. Sibi. M. P.; Kawashima, K.; Stanley, L. M. Org. Lett. 2009, 11, 3894-3897.
1) Enantioselective Enolate Protonations: Friedel-Crafts Reactions with a-Substituted Acrylates. Sibi, M. P.; Coulomb, J.; Stanley, L. M. Angew. Chem. Int. Ed. 2008, 46, 9913-9915.
https://doi.org/10.1002/ange.200804221
2) Tin-Free Enantioselective Radical Reactions Using Silanes. Sibi, M. P.; Yang, Y.; Lee, S. Org. Lett. 2008, 10, 5349-5352.
https://doi.org/10.1021/ol802154d
3) exo- and Enantioselective Diels-Alder Reactions: Pyrazolidinone Auxiliaries as a Means to Enhanced exo Selectivity. Sibi, M. P.; Nie, X.; Shackleford, J. P.; Stanley, L. M.; Bouret, F. Synlett 2008, 2655-2658.
4) Binding of Matrix Metalloproteinase Inhibitors to Extracellular Matrix: 3D-QSAR Analysis. Zhang, Y.; Lukacova, V.; Bartus, V.; Nie, A.; Sun, G.; Manivannan, E.; Ghorpade, S. R.; Jin, X.; Manyem, S.; Sibi, M. P.; Cook, G. R.; Balaz, S. Chem Biol Drug Des 2008, 72, 237-248.
https://doi.org/10.1111/j.1747-0285.2008.00710.x
5) Copper (II)-Catalyzed Exo and Enantioselective Cycloadditions of Azomethine Imines. Sibi, M. P.; Rane, D.; Stanley, L. M. Soeta, T. Org. Lett. 2008, 10, 2971-2974.
https://doi.org/10.1021/ol800904t
6) Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions. Stanley, L. M.; Sibi, M. P. Chem. Rev. 2008, 108, 2887-2902.
https://doi.org/10.1021/cr078371m
7) Chiral Lewis-Acid-Catalyzed Enantioselective Conjugate Radical Additions to a,b-Unsaturated 2-Pyridyl Ketones. Sibi, M. P.; Yang, Y-H. Synlett 2008, 83-88.
1) Enantioselective Radical Reactions. Stereoselective Aldol Synthesis from Cyclic Ketones. Sibi, M. P.; Nad, S. Angew. Chem. Int. Ed. 2007, 46, 9231-9234.
https://doi.org/10.1002/anie.200702976
2) Diastereoselective Conjugate Radical Additions to b-Pyranones. Sibi, M. P.; Yu, A. Synlett 2007, 3193-3197.
3) Organocatalysis in Conjugate Amine Additions. Synthesis of β-Amino Acid Derivatives. Sibi, M. P.; Itoh, K. J. Am. Chem. Soc. 2007, 127, 8064-8065.
https://doi.org/10.1021/ja071739c
4) Enantioselective 1,3-Dipolar Cycloadditions of Diazoacetates with Electron-Deficient Olefins. Sibi, M. P.; Stanley, L. M.; Soeta, T. Org. Lett. 2007, 9, 1553-1556.
https://doi.org/10.1021/ol070364x
5) Organocatalysis in Radical Chemistry. Enantioselective a-Oxyamination of Aldehydes. Sibi, M. P.; Hasegawa, M. J. Am. Chem. Soc. 2007, 129, 4124-4125.
https://doi.org/10.1021/ja069245n
6) Enantioselective Conjugate Addition of Hydrazines to a,b-Unsaturated Imides. Synthesis of Chiral Pyrazolidinones. Sibi, M. P.; Soeta, T. J. Am. Chem. Soc. 2007, 129, 4522-4523.
https://doi.org/10.1021/ja069312d
7) Enantioselective Diels-Alder Reactions. Effect of the Achiral Template on Reactivity and Selectivity. Sibi, M. P.; Chen, J.; Stanley, L. M. Synlett 2007, 298-302.
8) The Role of Achiral Pyrazolidinone Templates in Enantioselective Diels-Alder Reactions: Scope, Limitations, and Conformational Insights. Sibi, M. P.; Stanley, L. M.; Nie, X.; Venkatraman, L.; Liu, M.; Jasperse, C. P. J. Am. Chem. Soc. 2007, 129, 395-405.
https://doi.org/10.1021/ja066425o
9) Solution-Phase Parallel Synthesis of a Library of D2-Pyrazolines. Manyem, S.; Sibi, M.P.; Lushington, G. H.; Neuenswander, B.; Schoenen, F.; Aubé, J. J. Comb. Chem. 2007, 9, 20-28.
1) Enantioselective 1,3-Dipolar Cycloaddition of Nitrile Imines to a-Substituted and a,b-Disubstituted a,b-Unsaturated Carbonyl Substrates: A Method for Synthesizing Dihydropyrazoles Bearing a Chiral Quaternary Center. Sibi, M. P.; Stanley, L. M.; Soeta, T. Adv. Synth. Catal. 2006, 2371-2375.
https://doi.org/10.1002/adsc.200600307
2) Fluxional Additives: A Second Generation Control in Enantioselective Catalysis. Sibi, M. P.; Manyem, S.; Palencia, H. J. Am. Chem. Soc. 2006, 128, 13660-13661.
https://doi.org/10.1021/ja064472a
3) Pyrones to Pyrans: Enantioselective Radical Additions to Acyloxy Pyrones. Sibi, M. P.; Zimmerman, J. J. Am. Chem. Soc. 2006, 128, 13346-13347.
https://doi.org/10.1021/ja0648108
4) Enantioselective Conjugate Radical Addition to a'-Hydroxy Enones. Lee, S.; Lim, C. J.; Kim, S.; Subramaniam, R.; Zimmerman, J.; Sibi, M. P. Org. Lett. 2006, 8, 4311-4313.
https://doi.org/10.1021/ol061634z
5) Enantioselective Radical Reactions. Formation of Chiral Quaternary Centers. Sibi, M. P.; He, L. Synlett 2006, 0689-0692.
6) Enantioselective Radical Reactions. Evaluation of Nitrogen Protecting Groups in the Synthesis of β2-Amino Acids. Sibi, M. P.; Patil, K. Tetrahedron: Asymmetry 2006, 17, 516-519.
1) Stereoselective Conjugate Radical Additions: Application of a Fluorous Oxazolidinone Chiral Auxiliary for Efficient Tin Removal. Hein, J. E.; Zimmerman, J.; Sibi, M. P.; Hultin, P. G. Org. Lett. 2005, 7, 2755-2758.
https://doi.org/10.1021/ol050956k
2) Enantioselective Cycloadditions with a,b-disubstituted Acrylimides. Sibi, M. P.; Ma, Z.; Itoh, K.; Prabagaran, N.; Jasperse, C. P. Org. Lett. 2005, 7, 2349-2352.
https://doi.org/10.1021/ol050599d
3) Enantioselective Rhodium Enolate Protonations. A New Methodology for the Synthesis of b2-Amino Acids. Sibi, M. P.; Tatamidani, H.; Patil. K. Org. Lett. 2005, 7, 2571-2573.
https://doi.org/10.1021/ol050630b
4) Enantioselective Radical Methods for Lactone Synthesis. Use of Unprotected Haloalcohols as Radical Precursors. Sibi, M. P.; Guerrero, M. A. Synthesis 2005, 1528-1532.
5) An Entry to Chiral Dihydropyrazole Scaffolds: Enantioselective [3 + 2] Cycloaddition of Nitrile Imines. Sibi, M. P.; Stanley, L. M.; Jasperse, C. P. J. Am. Chem. Soc. 2005, 127, 8276-8277.
https://doi.org/10.1021/ja051650b
6) Enantioselective H-Atom Transfer Reactions. Synthesis of Formaldehyde Aldol Products. Sibi, M. P.; Patil, K. Org. Lett. 2005, 6, 1453-1456.
https://doi.org/10.1021/ol047347h
7) Novel Indole Chemistry in the Synthesis of Heterocycles. Gribble, G. W.; Saulnier, M. G.; Pelkey, E. T.; Kishbaugh, T. L. S.; Liu, Y.; Jiang, J.; Trujillo, H. A.; Keavy, D. J.; Davis, D. A.; Conway, S. C.; Switzer, F. L.; Roy, S.; Silva, R. A.; Obaza-Nutaitis, J. A.; Sibi, M. P.; Moskalev, N. V.; Barden, T. C.; Chang, L.; Simon, W.; Pelcman, B.; Sponholtz, III, W. R.; Chau, R. W.; Alison, B.; Garass, S. D.; Sinha, M. S.; McGowan, M. A.; Reese, M. R.; Harpp, K. S. Curr. Org. Chem. 2005, 9, 1493-1519.
https://doi.org/10.2174/138527205774370487
8) Enantioselective Addition of Nitrones to Activated Cyclopropanes. Sibi, M. P.; Ma, Z. Jasperse, C. P. J. Am. Chem. Soc. 2005, 127, 5764-5765.
https://doi.org/10.1021/ja0421497
9) Enantioselective Radical Addition/trapping Reactions with alpha,beta-Disubstituted Enoates. Synthesis of anti-Propionate Aldols. Sibi, M. P.; Petrovic, G.; Zimmerman, J. J. Am. Chem. Soc. 2005, 127, 2390-2391.
1) Enantioselective Diethylzinc Additions to Aldehydes Catalyzed by Chiral Relay Ligands. Sibi, M. P.; Stanley, L. A. Tetrahedron: Asymmetry 2004, 16, 3353-3356.
https://doi.org/10.1016/j.tetasy.2004.09.006
2) The nature, limits, and implications of asymmetric autocatalysis. Manyem, S.; Sibi, M. P. Chemtracts 2004, 17, 255-260.
3) Chiral Relay in Enantioselective Conjugate Radical Additions Using Pyrazolidinone Templates. How Does Metal Geometry Impact Selectivity? Sibi, M. P.; Prabagaran, N. Synlett 2004, 2421-2424.
4) Enantioselective Diels-Alder reactions of 3-(acyloxy)acrylates. Sibi, M. P.; Matsunaga, H. Tetrahedron Lett. 2004, 45, 5925-5929.
https://doi.org/10.1016/j.tetlet.2004.05.090
5) Application of Enantioselective Radical Reactions: Synthesis of (+)-Ricciocarpin A and B. Sibi, M. P.; He, L. Org. Lett. 2004, 6, 1749-1752.
https://doi.org/10.1021/ol0495772
6) Enantioselective Total Synthesis of (-)-Stemoamide. Sibi, M. P.; Subramanain, T. Synlett 2004, 1211-1214.
7) Chiral Lewis Acid Catalysis in Nitrile Oxide Cycloadditions. Sibi, M. P.; Itoh, K.; Jasperse, C. P. J. Am. Chem. Soc. 2004, 126, 5366-5367.
https://doi.org/10.1021/ja0318636
8) Enantioselective H-atom Transfer Reactions. Synthesis of b2-Amino Acids. Sibi, M. P.; Patil, K. Angew. Chem. Int. Ed. 2004, 43, 1235-1238.
https://doi.org/10.1002/anie.200353000
9) Exo Selective Enantioselective Nitrone Cycloadditions. Sibi, M. P.; Ma, Z.; Jasperse, C. P. J. Am. Chem. Soc. 2004, 126, 718-719.
https://doi.org/10.1021/ja039087p
10) Synthesis of Oxacycles by Tandem Radical Addition-Cyclization Reactions. Sibi, M. P.; Patil, K.; Rheault, T. R. Eur. J. Org. Chem. 2004, 372-384.
1) Tin-Free Radical-Mediated C–C-Bond Formations. Manyem, S.; Zimmerman, J.; Patil, K.; Sibi, M. P. Chemtracts 2003, 16, 819-826.
2) Enantioselective Radical Allylation Reactions using Chiral Lanthanide Lewis Acids. Sibi, M. P.; Manyem, S.; Subramaniam, R. Tetrahedron, 2003, 59, 10575-10580.
3) Enantioselective Radical Reactions. The Use of Metal Triflimides as Lewis Acids. Sibi, M. P.; Petrovic, G. Tetrahedron: Asymmetry, 2003, 15, 2879-2882.
4) Tandem radical reactions and ring-closing metathesis. Application in the synthesis of cyclooctenes. Sibi, M. P.; Aasmul, M.; Hasegawa, H.; Subramanian, T. Org. Lett. 2003, 5, 2883-2886.
5) Enantioselective Synthesis of alfa-beta-Disubstituted-b-Amino Acids. Sibi, M. P.; Prabagaran, N.; Ghorpade, S. G.; Jasperse, C. P. J. Am. Chem. Soc. 2003, 125, 11796-11797.
6) A New Class of Modular Chiral Ligands with Fluxional Groups. Sibi, M. P.; Zhang, R.; Manyem. S. J. Am. Chem. Soc. 2003, 125, 9306-9307.
7) Enantioselective Radical Conjugate Addition. A New Methodology for the Synthesis of Acetate Aldols. Sibi, M. P.; Zimmerman, J.; Rheault, T. R. Angew. Chem. Int. Ed. 2003, 42, 4521-4523.
8) Enantioselective Radical Reactions. Sibi, M. P.; Manyem. S.; Zimmerman, J. Chem. Rev. 2003, 103, 3263-3296.
9) Radical-Mediated Annulation Reactions. Rheault, T. R.; Sibi, M. P. Synthesis 2003, 803-819.
10) Chiral Relay: A Novel Strategy for the Control and Amplification of Enantioselectivity in Chiral Lewis Acid Promoted Reactions. Corminboeuf, O.; Quaranta, L.; Renaud, P.; Liu, M.; Jasperse, C. P.; Sibi, M. P. Chem. Eur. J. 2003, 9, 28-35.
11) Determination of Corrosion on Aluminum Alloy under Protective Coatings Using Fluorescent Probes. Sibi, M. P.; Zong, Z. Progress in Organic Coatings 2003, 47, 8-15.
1) Crotylations of a-Carbonyl Radicals with Crotylstannane. Sibi, M. P.; Miyabe, H. Org. Lett. 2002, 4, 3435-3438.
2) An Efficient Method for the Synthesis of Succinate Based MMP Inhibitors. Sibi, M. P.; Hasegawa, H. Org. Lett. 2002, 4, 3347-3349.
3) A Convenient Method for the Conversion of N-Acyl Oxazolidinones to Hydroxamic Acids. Sibi, M. P.; Hasegawa, H.; Ghorpade, S. R. Org. Lett. 2002, 4, 3343-3346.
4) Lanthanide Lewis Acid-mediated Enantioselective Conjugate Radical Additions. Sibi, M. P.; Manyem, S. Org. Lett. 2002, 4, 2929-2932.
5) Recent Advances in the Stereoselective Synthesis of b-Amino Acids. Liu, M.; Sibi, M. P. Tetrahedron 2002, 58, 7991-8035.
6) Temperature Dependent Reversal of Stereochemistry in Enantioselective Conjugate Amine Additions. Sibi, M. P.; Gorikunti, U.; Liu, M. Tetrahedron 2002, 58, 8357-8363.
7) Enantioselective Conjugate Addition of Silylketene Acetals to Enamidomalonates. Synthesis of b-Amino Acid Derivatives. Sibi, M. P.; Chen, J. Org. Lett. 2002, 4, 2933-2936.
8) Free Radical Mediated Conjugate Additions. Enantioselective Synthesis of (-)-Enterolactone, (-)-Arctigenin, (-)-Isoarctigenin, (-)-Nephrosetranic Acid and (-)-Roccellaric Acid. Sibi, M. P.; Liu, P.; Ji, J.; Hajra, S.; Chen, J. J. Org. Chem. 2002, 67, 1738-1745. Cover Article
9) Acyclic Diastereoselection in Prochiral Radical Addition to Prochiral Olefins. Sibi, M. P.; Rheault, T. R.; Chandramouli, S. V.; Jasperse, C. P. J. Am. Chem. Soc. 2002, 124, 2924-2930.
10) The Role of the Achiral Template in Enantioselective Transformations. Radical Conjugate Additions to a-Methylacrylates Followed by Hydrogen Atom Transfer. Sibi, M. P.; Sausker, J. B. J. Am. Chem. Soc. 2002, 124, 984-991.
1) Enantioselective Conjugate Addition of Organo-magnesium Amides to Enamidomalonates. Synthesis of Either Enantiomer of b-Amino Acid Derivatives. Sibi, M. P.; Asano, Y. J. Am. Chem. Soc. 2001, 123, 9708-9709.
2) Enantioselective Tandem Radical Reactions. Vicinal Difunctionalization in Acyclic Systems with Control over Relative and Absolute Stereochemistry. Sibi, M. P.; Chen, J. J. Am. Chem. Soc. 2001, 123, 9472-9473.
3) A New Approach to Enantiocontrol and Enantioselectivity Amplification. Chiral Relay in Diels-Alder Reactions. Sibi, M. P.; Venkatraman, L.; Liu, M.; Jasperse, C. P. J. Am. Chem. Soc. 2001, 123, 8444-8445
4) Enantioselective H-Atom Transfer Reactions. Synthesis of a-Amino Acids. Sibi, M. P.; Asano, Y.; Sausker, J. Angew. Chem. Int. Ed. 2001, 40, 1293-1296.
5) Enantioselective Conjugate Addition of Hydroxylamines to Pyrazolidinone Acrylamides. Sibi, M. P.; Liu, M. Org. Lett. 2001, 3, 4181-4184.
6) Radical-Mediated Annulation Reactions. A Versatile Strategy for the Preparation of a Series of Carbocycles. Sibi, M. P.; Chen, J.; Rheault, T. R. Org. Lett. 2001, 3, 3679-3681.
7) Highly Diastereoselective Radical Addition-Cyclization Strategy: Facile Synthesis of Substituted Furans. Sibi, M. P.; Rheault, T. R.; Miyabe, H.; Patil, K.; Jasperse, C. P. C. R. Acad. Sci. Ser II C 2001, 4, 581-584.
8) Reversal of Stereochemistry in Enantioselective Transformations. Can they be Planned or are they just Accidental. Sibi, M. P.; Liu, M. Cur. Org. Chem. 2001, 5, 719-755.
9) Enantioselective Synthesis of Peperomins A-D and Analog. Examination of Diastereoselective Cuprate Conjugate Additions to Enoyl Oxazolidinones. Sibi, M. P.; Johnson, M. D.; Punniyamurthy, T. Can. J. Chem. 2001, 79, 1546-1555.
1) Chiral Lewis Acid Catalyzed Conjugate Addition of N-benzylhydroxylamine to b-Aryl Enoates. Enantioselective Synthesis of b-Amino Acid Precursors. Sibi, M. P.; Liu, M. Org. Lett. 2000, 2, 3393-3396.
2) Enantioselective Conjugate Additions. Sibi, M. P.; Manyem, S. Tetrahedron 2000, 56, 8033-8061.
3) Higher Selectivity at Higher Temperatures! Effect of Precursor Stereochemistry on Diastereoselectivity in Radical Allylations. Insight into the Role of the Lewis Acid. Sibi, M. P.; Rheault, T. R. J. Am. Chem. Soc. 2000, 122, 8873-8879.
4) Enantioselective Synthesis of cis-N-Carbobenzyloxy-3-Hydroxyproline Ethylester. Sibi, M. P.; Christensen, J. W. in Catalysts for the Fine Chemical Industry Roberts, S. M., Ed., Wiley, Oxford, 2000.
5) A Short Synthesis of Both Enantiomers of Enterolactone. Sibi, M. P.; Liu, P.; Johnson, M. D. Can. J. Chem. 2000, 78, 133-139.
6) A New Methodology for the Synthesis of b-Amino Acids. Sibi, M. P.; Deshpande, P. K. J. Chem. Soc. Perkin Trans 1 2000, 1461-1466.
1) Stereoselective Conjugate Additions to Enoates. Sibi, M. P.; Liu, M. Enantiomer 1999, 4, 575-590.
2) Are Two Phenyl Groups Better than One? Synthesis and Applications of (R)-4-Diphenylmethyl-2-oxazolidinone. Sibi, M. P. Aldrichimica Acta 1999, 32, 93-101.
3) Enantiospecific Synthesis of (-)-Slaframine and Related Hydroxylated Indolizidines. Utilization of a Nucleophilic Alaninol Synthon Derived from Serine. Sibi, M. P.; Christensen, J. W. J. Org. Chem. 1999, 64, 6434-6442.
4) Free Radical-Mediated Intermolecular Conjugate Additions. Effect of the Lewis Acid, Chiral Auxiliary, and Additives on Diastereoselectivity. Sibi, M., P.; Ji, J.; Sausker, J. B.; Jasperse, C. P. J. Am. Chem. Soc. 1999, 121, 7517-7526.
5) Investigations of a Nucleophilic Alaninol Synthon Derived from Serine. Sibi, M. P.; Rutherford, D.; Renhowe, P. A.; Li, B. J. Am. Chem. Soc. 1999, 121, 7509-7516.
6) Reversal of Stereochemistry in Diethylzinc Addition to Aldehydes by a Simple Change of the Backbone Substituent in L-Serine Derived Ligands. Sibi, M. P.; Chen, J-x.; Cook, G. R. Tetrahedron Lett. 1999, 40, 3301-3304.
7) Enantioselective Reduction of Ketones. Examination of Bifunctional Ligands. Sibi, M. P.; Cook, G. R.; Liu, P. Tetrahedron Lett. 1999, 40, 2477-2480.
8) Enantioselective Radical Reactions. Sibi, M. P.; Porter, N. A. Acc. Chem. Res. 1999, 32, 163-171.
1) Chiral Lewis Acid Catalysis in Conjugate Additions of O-Benzylhydroxylamine to Unsaturated Amides. Enantioselective Synthesis of b-Amino Acid Precursors. Sibi, M. P.; Shay, J. J.; Liu, M.; Jasperse, C. P. J. Am. Chem. Soc. 1998, 120, 6615-6516.
2) Synthesis of Silicon Containing Alanines. Sibi, M. P.; Harris, B. J.; Shay, J. S.; Hajra, S. Tetrahedron, 1998, 54, 7221-7228.
1) Intermolecular Free Radical Reactions on Solid Support. Allylation of Esters. Sibi, M. P.; Chandramouli, S. V. Tetrahedron Lett. 1997, 38, 8929.
2) Enantioselective Intermolecular Free Radical Conjugate Additions. Application of a Pyrazole Template. Sibi, M. P.; Shay, J. J.; Ji, J. Tetrahedron Lett. 1997, 38, 5955.
3) A New Route to 3-Amino Sugars. A Concise Synthesis of L-Daunosamine and D-Ristosamine Derivatives. Sibi, M. P.; Lu, J.; Edwards, J. J. Org. Chem. 1997, 62, 5864.
4) Practical and Efficient Enantioselective Conjugate Radical Additions. Sibi, M. P.; Ji, J. J. Org. Chem. 1997, 62, 3800.
5) Regio-and Stereocontrolled Conjugate Radical Addition to a Desymmetrized Fumarate. An Efficient Synthesis of (-)-Nephrosteranic Acid and (-)-Roccellaric Acid. Sibi, M. P.; Ji, J. Angew. Chem. Int. Ed. Engl. 1997, 36, 274.
1) Chiral Lewis Acid Catalysis in Radical Reactions: Enantioselective Conjugate Radical Additions. Sibi, M. P.; Ji, J.; Wu, J. H.; Gurtler, S.; Porter, N. A. J. Am. Chem. Soc. 1996, 118, 9200-9201.
2) Enantiospecific Synthesis of Trisubstituted Butyrolactone Natural Products and their Analogs. Sibi, M. P.; Lu, J.; Talbacka, C. L. J. Org. Chem. 1996, 61, 7848.
3) Acyclic Stereocontrol in Radical Reactions. Diastereoselective Radical Addition/Allylation of N-Propenoyloxazolidinone. Sibi, M. P.; Ji, J. J. Org. Chem., 1996, 61, 6090.
4) Radical Methods in the Synthesis of Heterocyclic Compounds. Sibi, M. P.; Ji, J. Progress in Heterocyclic Chemistry, 1996, 8, 14.
5) Synthesis and Structural Characterization of Chiral Amine Alcohol Complexes of Aluminum. Atwood, D. A.; Gabbai, F. P.; Lu, J.; Remington, M. P.; Rutherford, D.; Sibi, M. P. Organometallics 1996, 15, 2308.
6) Participation of Organotin Lewis Acids in Radical Reactions: Manipulation of Rotamer Population in N-Enoyloxazolidinones. Sibi, M. P.; Ji, J. J. Am. Chem. Soc. 1996, 118, 3063.
7) Regio- and Stereoselective Functionalization of Linear Dicarboxylic Acid Derivatives. A Sequential Aldol-Lactonization Strategy for the Synthesis of (-)-Roccellaric Acid, (-)-Protolichesterinic Acid, and (-)-Methylenolactocin. Sibi, M. P.; Deshpande, P. K.; La Loggia, A. J. Synlett 1996, 343.
8) Acyclic Stereocontrol in Radical Reactions. r-selectivity using Oxazolidinone Auxiliaries. Sibi, M. P.; Ji, J. Angew. Chem., Int. Ed. Engl. 1996, 35, 190.
1) Preparation of Alkyne Derivatives via Organolithium Intermediates. Sibi, M. P. Lithium Link, Newsletter, 1995.
2) A New Chiral Oxazolidinone Derived from Diphenyl Alaninol. Aldol, Alkylation, and Diels-Alder Reactions. Sibi, M. P.; Deshpande, P. K.; Ji, J. Tetrahedron Lett. 1995, 36, 8965.
3) Synthesis of N-BOC-D-Diphenylalanine from L-Serine Methylester Hydrochloride. Sibi, M. P.; Deshpande, P. K.; LaLoggia, A. J.; Christensen, J. W. Tetrahedron Lett. 1995, 36, 8961.
4) Lewis Acid Mediated Intermolecular b-Selective Radical Additions to N-Enoyloxazolidinones. Sibi, M. P.; Jasperse, C. P.; Ji, J. J. Am. Chem. Soc. 1995, 117, 10779.
5) Intramolecular Hydrosilylations of b-Unsaturated Acyloxy Silanes. A Convenient Synthesis of (2S,3R)-N-BOC-3-Hydroxyproline Methyl Ester. Sibi, M. P.; Christensen, J. W. Tetrahedron Lett. 1995, 36, 6213.
6) Chemoselective Dieckmann-Like Condensations Using N-Methoxy-N-Methylamides. Sibi, M. P.; Christensen, J. W.; Kim, S.-G.; Eggen, M.; Stessman, C.; Oien, L. Tetrahedron Lett. 1995, 36, 6209.
7) a-Ketoamides and 1,2-Diketones from N,N'-Dimethoxy-N,N'-Dimethyl Ethanediamide. A Synthetic and Mechanistic Investigation. Sibi, M. P.; Marvin, M.; Sharma, R. J. Org. Chem. 1995, 60, 5016.
8) A Convenient Synthesis of N-Methoxy-N-Methylamides from Carboxylic Acids. Sibi, M. P.; Stessman, C. S.; Schultz, J. A.; Christensen, J. W.; Lu, J.; Marvin, M. Synth. Commun. 1995, 28, 1255.
1) A Convenient Synthesis of Both Enantiomers of trans-2,5-Bishydroxymethylpyrrolidine. Lipase Mediated Resolutions. Sibi, M. P.; Lu, J. Tetrahedron Lett. 1994, 35, 4915.
2) A New Electrophilic Alaninol Synthon. Synthesis of Protected D-Amino Alcohols From L-Serine. Sibi, M. P.; Rutherford, D.; Sharma, R., J. Chem. Soc. Perkin Trans 1, 1994, 1675.
3) Synthesis of Tetrahydrofuran Lignans. A Review. Gaboury, J. A.; Sibi, M. P. Journal of the Indian Institute of Science 1994, 74, 135.
1) Enantiocontrolled Synthesis of Burseran, Brassilignan, Dehydroxycubebin, and Other Unnatural Tetrahydrofuran Lignans in Both Enantiomeric Forms. Application of Intermolecular Nitrile Oxide Cycloadditions and Lipase Mediated Resolutions. Gaboury, J. A.; Sibi, M. P. J. Org Chem. 1993, 58, 2173.
2) Chemistry of N-Methoxy-N-Methylamides. Applications in Synthesis. Sibi, M. P. Org. Prep. Proced. Int. 1993, 25, 15.
1) Syntheses and Diels-Alder Cycloaddition Reactions of 4H-Furo[3,4-b]indoles. A Regiospecific Diels-Alder Synthesis of Ellipticine. Gribble, G. W.; Keavey, D. J.; Davis, D. A.; Saulnier, M. G.; Pelcman, B.; Barden, T. C.; Sibi, M. P.; Olson, E. R.; BelBruno, J. J. J. Org. Chem. 1992, 57, 5878.
2) Application of Enzymatic Methods for the Chiral Synthesis of 5-Substituted-2-Furanones. Sibi, M. P.; Gaboury, J. A. Tetrahedron Lett. 1992, 33, 5681.
3) A Novel Thermolytic Annulation of an Oxazolidinione: An Enantiospecific Synthesis of (-)-Slaframine. Sibi, M. P.; Christensen, J. W.; Li, B.; Renhowe, P. A. J. Org. Chem. 1992, 57, 4329.
4) Regio- and Stereocontrolled Hydroborations of Chiral Allyl Amines. Synthesis of Amino Alcohols. Sibi, M. P.; Li, B. Tetrahedron Lett. 1992, 33, 4115.
5) Reductions of a-Oxo-N-Methoxy-N-Methylamides. A Convenient Synthesis of 1,2-Diols. Sibi, M. P.; Sharma, R. Synlett 1992, 497.
6) N,N'-Dimethoxy-N,N'-Dimethylethanediamide: A Useful a-Oxo-N,O-Dimethyl Amide and 1,2-Dicarbonyl Synthon. Sibi, M. P.; Sharma, R.; Paulson, K. L. Tetrahedron Lett. 1992, 33, 1941.
7) Synthesis of Lignan Natural Products (±)Dehydroxycubebin and (±)Burseran by Intermolecular Nitrile Oxide Cycloaddition. Sibi, M. P; Gaboury, J. A. Synlett 1992, 83.
8) A Convenient Synthesis of 3-Alkyltetronic Acids from 3-Acyltetronic Acids. Sibi, M. P.; Sorum, M. T.; Bender, J. A.; Gaboury, J. A. Synth. Commun. 1992, 22, 809.
1) A New Nucleophilic Alaninol Synthon Derived From Serine. Sibi, M. P.; Renhowe, P. A. Tetrahedron Lett. 1990, 31, 7407.
2) Amino Acids as Precursors to Indolizidine Alkaloids. Sibi, M. P.; Christensen, J. W. Tetrahedron Lett. 1990, 31, 5689.
1) Palladium Mediated Biomimetic Synthesis of Narwedine. Holton R. A.; Sibi, M. P.; Murphy, W. J. J. Am. Chem. Soc. 1988, 110, 314.
1) Overriding Normal Friedel-Crafts Regioselectivity in Cycliacylation. Regiospecific Carbodesilylation and Parham Cyclization Routes to 7-Methoxy-1-indanols. Sibi, M. P.; Shankaran, K.; Alo, B. J.; Hahn, W. R.; Snieckus, V. Tetrahedron Lett. 1987, 28, 2933.
1) Anionic Aromatic Ring Annelation of o-Allyl Benzamides. Regiospecific Synthesis of Naphthols and Naphthoquinones. Sibi, M. P.; Dankwardt, J. W.; Snieckus, V. J. Org. Chem. 1986, 51, 271.
1) Combinational O-Aryl Carbamate and Benzamide Directed Ortho Metalation Reactions. Synthesis of Ochratoxin A and Ochratoxin B. Sibi, M. P.; Chattopadhyay, S.; Dankwardt, J. W.; Snieckus, V. J. Am. Chem. Soc. 1985, 107, 6512.
2) Dilithiated Synthons of Tertiary Benzamides, Phthalamides, and O,O'-Aryl Dicarbamates. Mills, R. J.; Horvath, R. F.; Sibi, M. P.; Snieckus, V. Tetrahedron Lett. 1985, 26, 1145.
3) Synthesis and Deamination of 7-12-Dihydrobenz[a]anthracen-7,12-imines. A New Benz[a]anthracene Synthesis. Gribble, G. W.; LeHoullier, C. S.; Sibi, M. P.; Allen, R. W. J. Org. Chem. 1985, 50, 1611.
1) Synthesis and Diels-Alder Reactions of 1,3-Dimethyl-1,4-(phenylsulfonyl)-4H furo (3,4-b)indole. A New Annulation Strategy for the Construction of Ellipticine and Isoellipticine. Gribble, G. W.; Saulnier, M. G.; Sibi, M. P.; Obaza-Nutaitis, J. A. J. Org. Chem. 1984, 49, 4518.
2) Benzamide Directed Ortho Metalation. A Route to the A/B Ring Synthon of Daunomycinone. Sibi, M. P.; Altintas, N.; Snieckus, V. Tetrahedron 1984, 40, 4593.
3) Ortholithiated Tertiary Benzamides. Magnesium Transmetalation and Synthesis of Phthalides and Isocoumarins Including Mellein and Kigelin. Sibi, M. P.; Miah, M. A. J.; Snieckus, V. J. Org. Chem. 1984, 49, 737.
1) Directed Ortho Metalation of Silyloxybenzamides: Anion Induced O---> C Silicon Rearrangement. Billedeau, R. J.; Sibi, M. P.; Snieckus, V. Tetrahedron Lett. 1983, 24, 4515.
2) Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy. 15N Chemical Shifts of Para-Substituted Hindered Anilines and Related Compounds. Sibi, M. P.; Prince, E. C.; LeMelle, J.; Lichter, R. L. Spectroscopy: An International Journal 1983, 2, 198.
3) The Directed Ortho Lithiation of O-Aryl Carbamates. An Anionic Equivalent of the Fries Rearrangement. Sibi, M. P.; Snieckus, V. J. Org. Chem. 1983, 48, 1935.
4) Synthesis and Deamination of 1,4-dihydronaphthalen-1,4-imines: A Convenient Naphthalene Synthesis. Gribble, G. W.; Sibi, M. P.; Kumar, S.; Kelly, W. J. Synthesis 1983, 502.
1) Reactions of Sodium Borohydride in Acidic Media; IX. Deoxygenation of 1,4-Epoxy-1,4-dihydronaphthalenes; A Convenient Naphthalene Synthesis. Gribble, G. W.; Kelly, W. J.; Sibi, M. P. Synthesis 1982, 143.
1) Dichlorocarbene-Induced Deamination of Naphthalen-1,4-imines and Anthracen-9-10-imines. Gribble, G. W.; Allen, R. W.; LeHoullier, C. S.; Eaton, J. T.; Easton, Jr., R. S.; Slayton, R. I.; Sibi, M. P. J. Org. Chem. 1981, 46, 1025.
1) Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy. 15N-19F Coupling Constants in Fluoropyridines and Fluoroanilines. Sibi, M. P.; Lichter, R. L. Org. Magn. Resonance 1980, 14, 494.
1) Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy. Natural Abundance Nitrogen-15 Chemical Shifts of Alkyl and Aryl Substituted Ureas. Sibi, M. P.; Lichter, R. L. J. Org. Chem. 1979, 44, 3017.
1) Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy. Natural Abundance Nitrogen-15 Chemical Shifts of Ring-Methylated N,N-dimethylanilines. Effect of Inhibition of Conjugation. Sibi, M. P.; Lichter, R. L. J. Org. Chem. 1977, 42, 2999.
1) A New Catalytic Process for the Conversion of Olefins to Carboxylic Acids. Sibi, M. P.; Boudjouk, P.; Ji, J. US Patent 5596111.
2) Chiral Ligands with Fluxional Groups. Sibi, M. P.; Manyem, S.; Jasperse, C. P.; Liu, M. Provisional patent application Filed on June 18, 2003.
3) Pyrazole Intermediates in a method of preparation of beta amino acids. Sibi, M. P.; Shay, J. J.; Liu, M.; Jasperse, C. P. US Patent 6191283. Issued 2/10/2001.
4) New Catalytic Methods for the Synthesis of Optically Active b-Amino Acids. Sibi, M. P.; Shay, J. J.; Liu, M.; Jasperse, C. P. US Patent 6080857. Issued 6/27/2000.
5) A New Method for the Preparation of Carboxylic Acids. Sibi, M. P.; Boudjouk, P.; Ji, J. US Patent 5939572. Issued 8/17/1999.
6) Diarylaminopropanediol and Diarylmethyloxazolidinone Compounds. Sibi, M. P.; Deshpande, P. K.; La Loggia, A. J. US Patent 5939554. Issued 8/17/1999.
7) Method for Preparation of Optically Active Diarylalanines. Sibi, M. P.; Deshpande, P. K.; La Loggia, A. J. US Patent 5623087
8) Beta Amino Acids and Methods and intermediates for making same. Sibi, M. P.; Jasperse, C. P.; Prabagaran, N.; Ghorpade, S. U.S. Pat. Appl. Publ. (2011), US 20110218342 A1 20110908.
9) Monomers and polymers derived from natural phenols. Chisholm, B. J.; Alam, S.; Sibi, M. P.; Sermadurai, S. U.S. Pat. Appl. Publ. (2014), US 20140296444 A1 20141002. US 20160023980A1. Published on 01/28/2016
10) Novel Monomers from Biomass. Sibi, M. P.; Sermadurai, S.; Zimmermann, N.; Serum, E.; Ma, G.; Moorthy, R.; Kalliokoski, K. Filed on August 8, 2014. US Application Serial No. 62/035,197. World-Wide patent applied
11) Programmed Degradation of Polymers Derived from Biomass. Sivaguru, J.; Sibi, M. P.; Webster, D. W.; Rajendran, S. K.; Raghunathan, R. Filed on November 3, 2014. US Application Serial No. 62/074,379. Patent application filed
1) Copper Lewis Acids in Organic Transformations. Iyanar, K.; Sibi, M. P. in Chiral Lewis Acids in Organic Synthesis, Mlynarski, J. Ed., Wiley, 2016.
2) Novel Bio-Based Polymers for Coating Applications. Kalita, H.; Halita, D.; Alam, S.; Chernykh, A.; Tarnavchyk, I.; Bahr, J.; Samanta, S.; Jayasooriyama, A.; Fernando, S.; Selvakumar, S.; Wickramaratne, D. S.; Sibi, M. P.; Chisholm, B. J. Eco-Friendly Green Coatings.
3) Synthesis and Characterization of Novel Soybean Oil-Based Polymers and Their Application in Coatings Cured by Autoxidation. Kalita, H.; Alam, S.; Halita, D.; Chernykh, A.; Tarnavchyk, I.; Bahr, J.; Samanta, S.; Jayasooriyama, A.; Fernando, S.; Selvakumar, S.; Popadyuk, A.; Wickramaratne, D. S.; Sibi, M. P.; Voronov, A.; Bezbaruch, A.; Chisholm, B. J. ACS Books “Soy-Based Chemicals and Materials”, Chapter, 2014, Chapter 16, pps 371-390; bk-2014-004903
4) Radical Addition Reactions. Subramanian, H.; Landais, Y.; Sibi, M. P. Comprehensive Organic Synthesis II, Volume 4, pp 699-741, 2014. doi:10.1016/B978-0-08-097742-3.00418-3
5) Chiral Copper Lewis Acids in Asymmetric Transformations. Adachi, S.; Moorthy, R.; Sibi, M. P. Copper Catalyzed Asymmetric Synthesis, Alexakis, A. Ed. pp 283-324, Wiley-VCH. 2014
6) Stoichiometric Auxiliary Ligands for Metals and Main Group Elements: Ligands for Magnesium and Calcium. Adachi, S.; Selvakumar, S.; Sibi, M. P. In Comprehensive Chirality, Carreira, E. M., Yamamoto, H. Eds, 2012, 3, 655-690.
7) Stereoselective Radical Reactions. Yang, Y.; Sibi, M. P. in Encyclopedia of Radicals in Chemistry, Biology and Materials, Chatgiliagolu, C.; Studer, A. Eds., Volume 2, pp 655-693, Wiley 2012
8) Chiral Bisoxazolines. Stanley, L. M.; Sibi, M. P. in Privileged Ligands, Zhou, Q. Ed.; Wiley New York, 2011, pp 171-219.
9) Free Radical Cyclization Reactions. Zimmerman, J.; Halloway, A.; Sibi, M. P. in Handbook of Cyclization Reactions, Ma, S. Ed.; Wiley-VCH, 2009.
10) Chiral Copper Lewis Acids in Organic Synthesis. Stanley, L. M.; Sibi, M. P. in New Lewis Acids in Organic Synthesis, Yamamoto, H.; Ishihara, K. Eds.; Wiley New York, 2007
11) Zimmerman, J.; Sibi, M. P. Topics in Current Chemistry 2006, 263 (Radicals in Synthesis 1), 107-162.
12) Preparation of Enantiopure beta-Amino Acids via Enantioselective Conjugate Addition. Liu, M.; Sibi, M. P. in Enantioselective Synthesis of b-amino Acids. Juaristi, E.; Soloshonok, V. Eds, Wiley, New York, 2005, pp 377-397.
13) Radical Reactions. Patil, K; Sibi, M. P., In Stereoselective Synthesis of Quaternary Centers, Christoffers, J.; Baro, A. Eds, Wiley-VCH, Weinheim, 2005.
14) b-Heteroatom-substituted Alkanamides. Sibi, M. P.; Manyem, S. Chapter 21.7, Science of Synthesis, Weinreb, S. M. Ed.; Georg Thieme Verlag: Stuttgart, 2005.
15) Radical Reactions in Combinatorial Chemistry. Ganesan, A.; Sibi, M. P. in Handbook for Combinatorial Chemistry, Golitz, P., Nicolaou, K. C.; Eds.; Wiley-VCH, Weinheim, 2001.
16) Enantioselective Radical Reactions. Sibi, M. P.; Rheault, T. R. In Radicals in Organic Synthesis, Renaud, P. and Sibi, M. P., Eds, Wiley-VCH, 2001.
17) Stereoselective Radical Reactions. Sibi, M. P.; Ternes, T. R. in Modern Carbonyl Chemistry, Otera, J., Ed, Wiley-VCH, 2000 pp 507-538.
18) Enantioselective Reduction of Ketones using Oxazaborolidines. Sibi, M. P.; Liu, P.; Cook, G.R. in Catalysts for the Fine Chemical Industry Roberts, S. M., Ed., Wiley, Oxford, 2000.
19) Copper Lewis Acids in Organic Synthesis. Sibi, M. P.; Cook, G. R. in Handbook of Lewis Acids, Yamamoto, H., Ed., Wiley-VCH, 2000.
20) Effect of Rotamer Population in Radical Reactions. Sibi, M. P.; Ji, J. In New Horizons in Organic Synthesis, Nair, V; Kumar, S. Eds., New Age International Publishers, New Delhi, 1997, pp 240-49.
21) Regiospecific Silicon-Mediated Route to 7-Methoxy-1-Indanols as Models for the Synthesis of Fluorene and Nitro-Fluorene PAH. Hahn, W. R.; Shankaran, K.; Sibi, M. P.; Snieckus, V. "Polynuclear Aromatic Hydrocarbons", Cooke, M.; Dennis, A. J.; Eds., 10th International Symposium, Battelle Press, Columbus, OH, 1987.
1) [3aR-[2(3'aR*,8'aS*),3a,8a]]-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole] and [3aS-[2(3'aR*,8'aS*),3'aa,8'aa]]-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole], RN00958.pub2. e-eros Update. Ma, G.; Sibi, M. P. e-EROS, Wiley, 2015
2) 8H-Indeno[1,2-d]oxazole, 2,2'-methylenebis[3a, 8a-dihydro-, (3aR, 3’aR, 8aS, 8’aS) & 8H-Indeno[1,2-d]oxazole, 2,2'-methylenebis[3a, 8a-dihydro-, (3aS, 3’aS, 8aR, 8’aR). Selvakumar, S.; Moorthy, R.; Ma, G.; Sibi, M. P. e-EROS, Wiley, 2013
3) Zinc Trifluoromethanesulfonimide. Yang, Y.; Sibi, M. P. Sibi, M. P. e-EROS, Wiley, 2011
4) Magnesium Trifluoromethanesulfonimide. Selvakumar, S.; Adachi, S.; Sibi, M. P. Sibi, M. P. e-EROS, Wiley, 2011
5) 2,6-Bis[(4R)-4,5-dihydro-4-phenyl-2-oxazolyl]pyridine and 2,6-Bis[(4S)-4,5-dihydro-4-phenyl-2-oxazolyl]pyridine. Takeda, N.; Sibi, M. P. e-EROS, Wiley, 2010
6) (S,S)-indapybox and (R,R)-indapybox. Coulomb, J. J.; Sibi, M. P. Electronic Encyclopedia of Reagents for Organic Synthesis 2008.
7) 5,5-Dimethyl-1-(Phenylmethyl)-3-Pyrazolidinone. Stanley, L. M.; Sibi, M. P. Electronic Encyclopedia of Reagents for Organic Synthesis, Wiley, 2006.
8) Ytterbium Triflate. Patil, K.; Sibi, M. P. Contribution to Encyclopedia of Reagents for Organic Synthesis, Wiley, 2004.
9) Contributions to Encyclopedia of Reagents for Organic Synthesis, Fourteen Reagents, Paquette, L. A., Ed. John Wiley, New York, 1995. pp 2721, 4831, 4837, 4840, 4841, 4842, 4843, 4844, 4845, 4847, 4848, 4849, 4850, 4854.